//M1//QN1//MCQ//DL0//EQ

(I) CH 3 CH 2 CH 2 NH 2 (II) (CH 3)3 N (III) (IV) CH 3 CH 2 CH 3 27. Which of the following compounds is the weakest Bronsted base?1. What is the number of isomers of primary amine having molecular formula C4H11N? 2. Which of the following is a secondary amine?3. C 7 H 9 N has ________ isomers.4. Methyl cyanide and methyl isocyanide show which type of isomerism? 5. Identify the IUPAC name of CH3CH2CH(CH3) NH2 .6. A secondary amine is a __________.7. Which is a secondary amine?8. What is the IUPAC name of vinyl cyanide?9. Which amine shows metamerism?10. Reduction of which compound forms a secondary amine? 11. In (CH3)3N the state of hybridization of N-atom and the spatial rearrangement of methyl groups around it are respectively.12. What is the C–N–C bond angle in trimethyl aniline?13. Which of the following is a secondary amine?14. What causes bond angles to decrease in amine compounds? 15. Displacement of the hydrogen of ammonia by hydrocarbon group form __________.16. If one hydrogen atom of NH3 is replaced by an alkyl or aryl group, it is called __________ amine.17. Identify the type of amine N – H18. _______ groups are same in simple amines.19. Which of the following amines is a mixed amine?20. What does C3H9N represent?21. Which of the following statements is false?22. What is the IUPAC name of compound?23. Identify the correct IUPAC name of

CH2 = CH – CH2 – NH – CH3.24. Identify the IUPAC name of the following: 25. The IUPAC name of is:

26. Identify the IUPAC name of isopropyl amine:
27. Which of the given processes differs from the others with respect to the formation of amine compounds?28. Primary aromatic amines cannot be prepared by which of the following processes?29. Which is the alkanamide compound that yields 1–phenyl ethyl amine by Hofmann reaction?30. The reaction of an alkylhalide with KCN leads to the formation of product by the reduction of that product will get?31. Reduction of the product obtained by dehydration of the amide gives a ________. 32. Which of the given nitrogen containing compound will give Hofmann reaction?33. Acetamide treated independently with the following reagents, which of the reagents will yield methyl amine?34. Which of the following substances can't be made by Gabriel phthalimide synthesis?35. Which of the following reagents will convert nitromethane into methyl amine?36. A given nitrogen containing aromatic compound ‘A’ reacts with Sn/HCl‚ followed by HNO2 to give an unstable compound ‘B’ . ‘B’ on treatment with phenol, forms beautiful coloured compound 'C' with the molecular formula C 12 H 10 N 2 O. Identify the compound.37. _________ compound will give Hofmann bromamide reaction.38. Which amine can not be made by gabriel synthesis?39. Aceto nitrile reduction gives ________.40. Which reagent is useful for the formation of methanamine from acetamide?41. What happens when nitro alkane is reduced?42. CH 3 CH 2 CONH 2 main organic product [X]. what is X here? 43. CH 3 – CH 2 – CH 2 – NO 2 X
is given reaction = ________.
44. Why is Fe/HCl is more useful than Sn/HCl for the reduction of nitro compounds under present condition?45. Free amine is obtained by treating ammonium salt with whom?46. X, in given reaction
X =
47. Which order of reactivity of a halide with an amine is correct?48. Which of the aryl halide and alkyl halide is less reactive towards nucleophilic substitution reaction?49. How primary amines can be obtained from the mixture of ammonium salts obtained during ammonolysis?50. Amide can be converted to amine by which process?51. By which of the following does the process of LiAlH4 give a secondary amine (2°)?52. CH 3 C ≡ N in this
reaction X = ________.
53. R–X X Y in this reaction Y = ________.54. X ;
In the reaction X = ________.
55. CH 3 NO 2 CH 3 – X In this reaction X = ________. 56. CH 3 – CO – N , Product in this reaction is ________.57. In Hofmann reaction, the amine formed has how many more carbon atoms than the present amide?58. + Br 2 + 4NaOH ________.59. Which of the following processes will not give a primary amine?60. Gabriel phthalimide reaction is useful for the preparation of which of the following compounds?61. Which of the following amines cannot be prepared by Gabriel phthalimide reaction?62. Benzyl amine can be produced by which of the following processes?63. Gabriel phthalimide synthesis method is useful for whom?64. Reduction of which amide yields compound?65. Propanoic acid X

Y Z, Z = ________.66. By which reaction amine is not obtained?67. 2-Bromopropane x y,
then IUPAC name of y is:
68. Which of the following has the lowest boiling point?69. Aniline is soluble in.70. Which of the following will have the highest boiling point?71. What is the state of very low molecular weight aliphatic amines?72. (i) C 2 H 6 (ii) CH 3 CH 2 NH 2 (iii) C 2 H 5 OH Which is the correct ascending order of the boiling point for the given three compounds?73. Which is the correct descending order of boiling point for amine compounds having the same molecular formula?74. Which type of isomerism is present in 1-propane amine and 2-propane amine?75. Which of the following types of amine compounds have metamerism isomerism?76. Which of the following order is correct with respect to polarity?77. What is the difference between the electronegativity of O and N?78. Which amine has the lowest boiling point among isomeric amines?79. Which of the following has intermolecular

H bonding?80. Among ethyl alcohol, ethyl amine and formic acid, which has the highest boiling point?81. How do lower amine compounds smell?82. Which compound has a bad odor?83. Which compound is soluble in alkali? 84. Which compound does not react with Hinsberg's reagent?85. What is obtained by the reaction of aniline with acetyl chloride?86. Which compound does not give carbyl amine test?87. Which of the given amine compounds is most basic?88. X + Y + Z.

If X , Y and Z get 47%, 2% and 51% respectively then what will be the product respectively?
4–Nitro aniline
4–Nitro aniline
3–Nitro aniline
2–Nitro aniline
89. Which order of basicity is correct in aqueous solution? 90. Which compound does not react with Hinsberg's reagent?91. Alcohol is formed by the reaction of which compound with nitrous acid? 92. An organic compound ‘A’ on reduced gives compound 'B' which on reaction with chloroform and potassium hydroxide forms 'C'. The compound 'C' on catalytic reduction gives N-Methylaniline, The compound 'A' is:93. CH3CH2Cl X Y Z. In the given reaction identify the product 'Z'. 94. State the end result of the given reaction series Ethanamine A B C.95. An organic compound ‘A’ on reduction gave a ‘B’ compound‚ upon treatment with HNO2 gave ethanol, Identify the compound 'A'. 96. Which statement is false for primary amine compounds?97. What is the product of benzoylation of N-ethyl ethanamine?98. Benzanilide is produced by the process between which substances?99. Which of the given functional group increases the basic strength of the aniline?100. Which of the following reactions of aniline gives zwitterion? 101. The reaction of amine compound with benzene sulphonyl chloride yields a solid compound insoluble in alkali which amine compound would it be?102. CH3CH2NH2 contains basic NH2 group but CH3CONH2 does not contain basic NH2 group because,103. Identify the main product 'C' in the following reaction:
Aniline A B C.
104. In which of the following process will cyanide be obtained as the main product? 105. Ethyl amine and diethyl amine cannot be differentiated by which test?106. Aniline when acetylated, the product on nitration followed by alkaline hydrolysis gives:107. Which of the following compounds does not react with Hinsberg's reagent?108. Which is a stronger base than amine?109. What is the reaction of ethanamine with chloroforms and alcoholic KOH?110. Which method is not for the forming amines or separating amines?111. Find the strongest base.112. Which of the following amine reacts with NaNO2 and HCl at 273-278 K–to give alcohol?113. Which of the following is the correct order based on the amount of product produced by nitration of aniline?
> m-Nitroaniline
> p-Nitroaniline
> o-Nitroaniline
> o-Nitroaniline
114. Whose pKb value is highest?115. Benzene sulphonyl chloride is called a_______.116. 1° Amine are converted to 3° amine by_________.117. The activating effect of the amino group in aniline is reduced by ________.118. Which of the following will have the highest pKb?119. Which of the following is a foul smelling and poisonous substance?120. Which of the following compounds gives alcohol with NaNO2 and HCl?121. What is the relative basicity of alkanamine and ammonia?122. On what does the basicity of an amine depends?123. Which property makes amine compounds behave as Lewis base?124. What are amine compounds in water?125. Below are the values of pKb for same bases, select the lowest base accordingly:126. Which of the following is the correct ascending order of basicity of aqueous solution?127. Choose the correct order of basic strength in the vapour phase (non-aqueous solution) for the following amine compounds.128. Which of the following is the strongest base in aqueous solution?129. Which of the following is the most basic?130. Which of the following is the most basic?131. Which of the following is the strong base?132. Which of the following is a weak base?133. Which of the following is the correct order of basicity for ethyl substituted amine? 134. What is the end product 'Y' in the following sequential reaction?
CH 3 CH 2 CH 2 CONH 2 X Y
135. In this reaction X = ________.136. C 6 H 5 – NH 2 + C 6 H 5 COCl Y In this reaction Y = ________.137. R – NH2 + CHCl3 + 3KOH X In this reaction X = ________.138. Which of the following procedures is not useful in the preparation of amine compounds or separation of amine compounds?139. In the given reaction, identify 'Z'. C 6 H 5 NH 2 X Y Z 140. p-toluidine ?
Identify the product in the given reaction.
141. CH3CH2Cl X Y Z
In the above reaction, identify the 'Z'.
142.
In this reaction X = ________.
143. Acetanilide X Y
In the given reaction Y = ________.
144. C 6 H 5 NH 2 X
In this reaction X = ________.
145. Aniline does not undergo which of the following reactions?146. What is the used reagent for the separation of 1°, 2°, 3° amines?147. Which of the following substance will react with benzene sulphonyl chloride?148. Aniline X Y
In this reaction X = ________.
149. Which of the following amines does not react with acetyl chloride?150. In below reaction identify the product: ?151. Why diazonium salts are used immediately?152. CH3CH2NH2 + CHCl3 + 3KOH → x + y + 3H2O.

In this reaction x and y compounds are?153. Chemical reactions of propionic acid are given below. Identify the end product (D)? CH 3 CH 2 COOH B C D 154. Which of the following diazonium salts are stable at room temperature? 155. What is the common formula of diazonium salt?156. What will be obtained by heating benzene diazonium chloride and hypo phosphorous acid at room temperature?157. Which compound is not made by Sandmeyer's reaction?158. What is p-hydroxy azo benzene?159. Which of the following compounds will give dye test?160. Aniline A B C In given reaction identify the product D and give its structure.161. How many total isomers of organic compounds having molecular formula C7H9N will react with nitrous acid?162. Identify the compound 'B' in the following conversion. Aniline A B 163. C6H5NH2 A B.

In this reaction product B _______.
164. Aniline is reacted with bromine water and the resulting product is treated with an aqueous solution of sodium nitrite in the presence of dilute hydrochloric acid. The compound so formed is reacted with a tetra fluoro borate which is subsequently heated. The final product is?165. C6H5N2+Cl – C6H5Cl + N2:

Identify the name of the reaction.166. C6H5N2+Cl – C6H5Cl + N2 + CuCl: Identify the name of the reaction. 167. ArN2+ Cl– ArCl + N2. Identify the name of the reaction _________.168. Which of the following is a product of Gattermann reaction?169. Which of the following is the structural formula of orange azo dye?

(A)
(B)
(C)
(D)
170. ________ is the Gattermann reagent?171. X
In this reaction X = ________.
172. Benzene diazonium chloride is a ________ solid.173. At what temperature does benzene diazonium chloride become stable?174. Which of the following diazonium salts is stable at room temperature?175. C 6 H 5 N 2+Cl– X
In this reaction X = ________.
176. Which of the following reagent is used in Gattermann reaction?177. The reaction involving the treatment of benzene diazonium chloride with copper powder and HCl gives chlorobenzene or bromo benzene termed as:178. C 6 H 5 N 2+Cl– X
In this reaction X = ________.
179. Benzene diazonium fluoroborate In this reaction X = ________.180. Y
In the reaction Y = ________.
181. Benzene diazonium chloride
X In this reaction X = ________.
182. C 6 H 5 N 2+Cl– X
In this reaction X = ________.
183. Which of the following is a light yellow azo dye? 184. What product will be getting by the reaction of primary aliphatic amine and nitrous acid?185. ________ reacts with phenol to give an azo dye.186. Which of the following reaction is incorrect of Aryl diazonium salt?187. Identify the W, X, Y, Z in the given reaction: nitro be nzene W X Y Z
X = 2, 4, 6-Tribromoaniline
Y = 2, 4, 6-Tribromobenzene diazonium chloride
Z = 1, 3, 5-Tribromobenzene
X = 2, 4, 6-Tribromobenzene
Y = 2, 4, 6-Trichlorobenzene
Z = 2, 4, 6-Trichlorophenol
X = p-bromoaniline
Y = p-bromobenzene diazonium chloride
Z = p-bromophenol
X = p-bromoaniline
Y = p-bromobenzene diazonium chloride
Z = bromobenzene
188. Identify the U in below reaction:
189. In below reaction which two products are same?
190. Assertion : Aliphatic amines are more basic than aromatic amines.
Reason : The lone pair of electrons on the nitrogen atom in aliphatic amines is delocalized over the aromatic ring through resonance.
191. Assertion : Ortho-substituted aniline is less basic than aniline.
Reason : Ortho-substituted aniline experiences both electronic effects and steric hindrance, reducing its basicity.
192. Assertion : Electron-releasing groups increase the basic strength of aniline derivatives.
Reason : Electron-releasing groups donate electron density to the benzene ring, making the lone pair on nitrogen more available for protonation.
193. Assertion : The basic strength of methylamine is higher than ammonia in aqueous solutions.
Reason : Methylamine forms stronger hydrogen bonds with water compared to ammonia.
194. Assertion : Secondary amines have lower boiling points than primary amines of similar molecular mass.
Reason : Secondary amines cannot form intermolecular hydrogen bonds.
195. Assertion : Aniline reacts with bromine water to give 2,4,6-tribromoaniline.
Reason : Aniline is a strong electron-withdrawing group.
196. Assertion : p-Nitroaniline is less basic than p-methoxyaniline.
Reason : T he -NO 2 group at the para position is an electron-withdrawing group, whereas -OCH 3 is an electron-releasing group.
197. Assertion : Tertiary amines are less soluble in water compared to primary amines of similar molecular weight.
Reason : Tertiary amines lack hydrogen atoms for hydrogen bonding with water.
198. Assertion : Aniline is less basic than ammonia.
Reason : The lone pair of electrons on the nitrogen atom in aniline participates in resonance with the benzene ring, reducing its availability for protonation.
199. Assertion : p-Toluidine is more basic than aniline.
Reason : The –CH 3 group in p-toluidine donates elec tron density to the benzene ring, increasing the availability of the lone pair on nitrogen.
200. Assertion : Methylamine has a higher boiling point than dimethylamine.
Reason : Methylamine forms stronger hydrogen bonds compared to dimethylamine due to more hydrogen atoms on the nitrogen.
201. Assertion : Benzenediazonium chloride is stable at low temperatures.
Reason : At low temperatures, the decomposition of benzenediazonium chloride is kinetically hindered.
202. Assertion : The boiling points of primary amines are higher than those of alcohols of similar molecular weight.
Reason : Hydrogen bonding in amines is stronger than in alcohols due to the higher electronegativity of nitrogen compared to oxygen.
203. Assertion : The reaction of nitrous acid with primary aliphatic amines produce alcohols.
Reason : Primary aliphatic amines form unstable diazonium salts, which decompose to give alcohols.
204. Assertion : Amines can be distinguished by the Hinsberg test.
Reason : Hinsberg’s reagent reacts differently with primary, secondary, and tertiary amines, forming distinguishable products.
205. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Primary amines can form hydrogen bonds with water.
(ii) Secondary amines have higher boiling points than primary amines.
(iii) Aniline reacts with bromine water to form 2,4,6-tribromoaniline.
(iv) Aromatic amines are less basic than aliphatic amines.
206. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Aniline is a weaker base than ammonia.
(ii) Electron-donating groups increase the basicity of aniline.
(iii) The –NO 2 group at the meta position decreases the basicity of aniline.
(iv) Tertiary amines are less soluble in water than primary amines.
207. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Benzenediazonium chloride is stable at room temperature.
(ii) Diazonium salts decompose to form alcohols in aqueous solutions.
(iii) The diazotization reaction occurs at

273–278 K.

(iv) Benzenediazonium chloride reacts with phenol to form an azo compound.
208. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Amines can act as nucleophiles in organic reactions.
(ii) Tertiary amines cannot form hydrogen bonds.
(iii) Primary amines give positive Carbylamine tests.
(iv) Electron-withdrawing groups increase the basicity of aniline.
209. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Hinsberg’s reagent reacts with all types of amines.
(ii) Secondary amines form N-alkyl sulphonamide with Hinsberg’s reagent.
(iii) Tertiary amines are insoluble in water.
(iv) Aniline is a primary aromatic amine.
210. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Ortho-substituted anilines are more basic than aniline.
(ii) Electron-donating groups at the para position increase the basicity of aniline.
(iii) Methylamine is a stronger base than ethylamine.
(iv) Aliphatic amines are generally stronger bases than aromatic amines.
211. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Primary amines can be prepared by Gabriel phthalimide synthesis.
(ii) Gabriel synthesis can also produce secondary amines.
(iii) Reduction of nitriles yields primary amines.
(iv) Ammonia reacts with alkyl halides to produce primary amines directly.
212. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Tertiary amines have no N-H bonds.
(ii) The boiling point of an amine increases with molecular weight.
(iii) Amines are less soluble in water than alcohols of similar molecular weight.
(iv) Aromatic amines exhibit a higher boiling point than aliphatic amines of similar size.
213. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Aromatic amines undergo electrophilic substitution reactions.
(ii) The amino group in aniline is

meta-directing in electrophilic substitution reactions.

(iii) Bromination of aniline in aqueous solution forms 2,4,6-tribromoaniline.
(iv) Nitration of aniline produces predominantly para-nitroaniline.
214. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Amines can act as Bronsted bases.
(ii) The pK b value of aliphatic amines is higher than aromatic amines.
(iii) Ethylamine reacts with nitrous acid to give ethyl alcohol.
(iv) Tertiary amines react with nitrous acid to form alcohols.
215. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Amines are more basic in aqueous solution than in the gaseous state.
(ii) Ammonia is less basic than methylamine.
(iii) Tertiary amines are always more basic than secondary amines.
(iv) Benzylamine is an aromatic amine.
216. Select the correct option using T (True) or

F (False) symbol for the following statements.

(i) Diazonium salts are used in azo dye synthesis.
(ii) Aliphatic diazonium salts are more stable than aromatic diazonium salts.
(iii) Phenols react with diazonium salts to form coloured azo compounds.
(iv) Azo coupling is an electrophilic substitution reaction.
Class 12 Chemistry (Part 2) 018

(A) TFTT (B) FTTT (C) TTFT (D) FTFT

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